open access publication

Article, Early Access, 2023

Hybrid catalysis for enantioselective Baeyer-Villiger oxidation and stereoselective epoxidation: a Cp*Ir complex to fuel FMN and FAD reduction for flavoprotein monooxygenase modules

REACTION CHEMISTRY & ENGINEERING, ISSN 2058-9883, 2058-9883, 10.1039/d3re00411

Contributors

Roellig, Robert (Corresponding author) [1] [2] [3] Paul, Caroline Emilie 0000-0002-7889-9920 [4] Rousselot-Pailley, Pierre [1] [2] [3] Kara, Selin 0000-0001-6754-2814 (Corresponding author) [5] [6] Alphand, Veronique (Corresponding author) [1] [2] [3]

Affiliations

  1. [1] Aix Marseille Univ, CNRS, Cent Marseille, ISM2,UMR 7313, Marseille, France
    2. [NORA names: France; Europe, EU; OECD];
  2. [2] Aix Marseille Univ, CNRS, Cent Marseille, ISM2,UMR 7313, Marseille, France
    3. [NORA names: France; Europe, EU; OECD];
  3. [3] Aix Marseille Univ, CNRS, Cent Marseille, ISM2,UMR 7313, Marseille, France
    4. [NORA names: France; Europe, EU; OECD];
  4. [4] Delft Univ Technol, Dept Biotechnol, Biocatalysis Sect, Van Der Maasweg 9, NL-2629 HZ Delft, Netherlands
    5. [NORA names: Netherlands; Europe, EU; OECD];
  5. [5] Aarhus Univ, Dept Biol & Chem Engn, Biocatalysis & Bioproc Grp, Gustav Wieds Vej 10, DK-8000 Aarhus, Denmark
    6. [NORA names: AU Aarhus University; University; Denmark; Europe, EU; Nordic; OECD];

Abstract

Taking advantage of the standalone capacity of the two-component flavoenzyme oxygenation module, we extended the scope of the pH and oxygen robust iridium complex, Cp*Ir(bpy-OMe)H+ to drive enzymatic reactions from a low-cost hydride source.

Data Provider: Clarivate

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