open access publication

Article, 2024

Self-assembly of a supramolecular spin-crossover tetrahedron

DALTON TRANSACTIONS, ISSN 1477-9226, 1477-9226, Volume 53, 23, Pages 9792-9797, 10.1039/d4dt00578c

Contributors

Nielsen, Hannah H. [1] [2] Vilarino, Pol [2] Rodriguez, Gemma [2] Trepard, Florian [2] Roubeau, Olivier (Corresponding author) [3] [4] Aromi, Guillem (Corresponding author) [2] Aguila, David (Corresponding author) [2]

Affiliations

  1. [1] Aarhus Univ, Dept Chem, DK-8000 Aarhus, Denmark
    2. [NORA names: AU Aarhus University; University; Denmark; Europe, EU; Nordic; OECD];
  2. [2] Univ Barcelona IN2UB, Inst Nanosci & Nanotechnol, Barcelona 08007, Spain
    3. [NORA names: Spain; Europe, EU; OECD];
  3. [3] INMA, CSIC, Plaza San Francisco S-N, Zaragoza 50009, Spain
    4. [NORA names: Spain; Europe, EU; OECD];
  4. [4] Univ Zaragoza, Plaza San Francisco S-N, Zaragoza 50009, Spain
    5. [NORA names: Spain; Europe, EU; OECD]

Abstract

A new mononuclear iron(ii) SCO compound featuring H-bonding donor and acceptor units has been synthesized and exploited to produce a purely supramolecular switchable [Fe4] tetrahedron. Magnetic and crystallographic measurements evidence a singular magnetic behavior for each of the four Fe(ii) centers of the generated architecture and underscore the potential of this strategy to develop novel SCO materials.

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